CH 817 : Advanced Co-ordination Chemistry

New, Autumn elective

Syllabus

Background of co-ordination chemistry. Bond, structure and chemical reactivity of metal complexes, physical properties of metal complexes, synthesis, structure and function of 3D coordination architectures, Synthesis and structure of coordination polymers. 

Supramolecular design, host-guest chemistry, molecular self-assembly, supramolecular applications in biomedical sciences, catalysis, nanoscale devices. Magneto-chemistry of coordination compounds, origin and classes of magnetism, spin and orbital contribution to magnetic moments, measurement of magnetic susceptibility using common experimental protocols, temperature dependency of magnetic susceptibility, single-ion magnetic properties. Superexchange interactions, Single Molecule Magnets and its related phenomena in molecular clusters.

Text References

J. W. Steed and J. L. Atwood, Supramolecular Chemistry, 2nd edition, Wiley VCH Inc, 2009.

2. P. J. Cragg, Supramolecular Chemistry: From Fiological Inspiration to Biomedical Applications, Springer Science, 2010.

3. O. Kahn, Molecular Magnetism, Wiley-VCH Inc, 1993.

4. D. Gatteschi, R. Sessoli and J. Villain, Molecular Nano Magnets, Oxford University Press, 2006.

5. R. S. Drago, Physical Methods for Chemists, Saunders, 1992.