CH 806 : Molecular Photochemistry

Spring elective.

Syllabus

Introduction to molecular photochemistry: Photochemical laws, electronic absorption spectra of organic and inorganic compounds. Radiative and non-radiative processes. Nature of electronically excited states (singlets and triplets). Jablonski diagrams, Kasha’s rule, experimental methods in photochemistry.

Organic photochemistry: The intermolecular processes: excimers, exciplexes, energy transfer processes, electron or proton transfer reactions. Fluorescence, phosphorescence and thermally activated delayed fluorescence in organic systems. Effect of solvents on these processes. Fluorescence quenching mechanisms (static and dynamic), Stern-Volmer analysis. Photochemical name reactions: Norrish type I and II cleavage, Patero-Buchi reaction, de Mayo reaction etc.

Frontier orbital correlation diagrams of photochemical reactions, photochemistry of alkenes and dienes, photochemistry of carbonyl compounds, photochemistry of aromatic compounds, photosynthesis.

Photochromism. Bioluminescent and photo-luminescent reactions.

Introduction to inorganic photochemistry. photochemical kinetics. Photoelectrochemistry of excited states  of  inorganic compounds. Redox reactions. Photosensitization. Photochemical reactions: substitution, decomposition and fragmentation, rearrangement, and redox reactions. Photochemistry in  biological processes and their model studies.

Text References

1. N. J. Turro, V. Ramamurthy and J. C. Scaiano, Modern Molecular Photochemistry of Organic Molecules, Viva Books, New Delhi, 2017.

2. B. Dinda, Essentials of Pericyclic and Photochemical Reactions, Springer International Publishing AG Cham, Switzerland, 2017.

3. V. Balzani, P. Ceroni, A. Juris, Eds, Photochemistry and Photophysics: Concepts, Research, Applications, Wiley-VCH Weinheim, Germany, 2014.

4. S. Saha, Ed, Molecular Photochemistry-​Various Aspects, In Tech Rijeka, Croatia, 2012.

5. A. Griesbeck, M. Oelgemoller, F. Ghetti, Eds, CRC Handbook Of Organic Photochemistry and Photobiology, Third Edition, Volume 1, CRC Press, Boca Raton, Fla. 2012.

6. A. Griesbeck, M. Oelgemoller, F. Ghetti, Eds, CRC Handbook Of Organic Photochemistry and Photobiology, Third Edition, Volume 2, CRC Press, Boca Raton, Fla. 2012.

7. A. Albini, M. Fagnoni, Eds, Handbook of Synthetic Photochemistry, Wiley-VCH Verlag GmbH, Weinheim, Germany, 2010.

8. V. Balzani, S. Campagna, Eds, Photochemistry and Photophysics of Coordination Compounds II, In: top. Curr. Chem. 2007, 281, Springer GmbH Berlin, Germany, 2007.

9. V. Balzani, S. Campagna, Eds, Photochemistry and Photophysics of Coordination Compounds I, In: Top Curr. Chem. 2007; 280, Springer GmbH, Berlin, Germany.

10. S. Kumar, V. Kumar and S. P. Singh, Pericyclic Reactions, 1st Edition, Academic Press, Elsevier Inc, 2016.