Seminar by Prof. Marc Robert, Senior member (Innovation Chair) at Institut Universitaire de France on "Reduction of CO2 with molecular catalysts beyond 2 electrons and 2 protons".

13 Oct 2023
Seminar Room # 350, second floor annex

Speaker: Prof. Marc Robert
Professor at Université Paris Cité (Paris, France)
and a Senior member (Innovation Chair) at Institut
Universitaire de France (IUF).

Title: "Reduction of CO2 with molecular catalysts beyond 2
electrons and 2 protons".

Day and Date: Friday, October 13, 2023

Time: 5.00 PM.

Venue: Seminar room, room no. 350, Chemistry Department
(second floor, Annex)

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Hosted by Prof. Arnab Dutta

Talk Title : "Reduction of CO2 with molecular catalysts beyond 2 electrons and 2 protons".
Abstract
Reduction of carbon dioxide has as main objective the production of useful organic compounds and fuels - *renewable fuels* - in which solar energy would be stored. Molecular catalysts can be employed to reach this goal, either in photochemical or electrochemical (or combined) contexts. They may in particular provide excellent selectivity thanks to easy tuning of the electronic properties at the metal and of the ligand second and third coordination sphere. Recently we have been shown that such molecular catalysts may also be tuned for generating highly reduced products such as formaldehyde, methanol and methane, leading to new exciting advancements. Obtaining C-C coupling products is an additional intriguing possibility. Our recent results will be discussed, using earth abundant metal (Fe, Co) porphyrins and phthalocyanines as well as related complexes as catalysts.